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Yashasvi Singh

Steam Methane Reforming (SMR) vs. Methane Pyrolysis: The Path to Greener Hydrogen

Steam Methane Reforming (SMR) vs. Methane Pyrolysis

Methane Pyrolysis
Methane Pyrolysis

Hydrogen, as a clean energy carrier, holds immense potential in our quest for a greener and more sustainable future. It can be produced from various sources and processes, but not all hydrogen production methods are created equal. In this blog, we'll delve into the different methods of hydrogen production and highlight the emergence of methane pyrolysis as a more sustainable alternative. Let's dive deep into Steam Methane Reforming (SMR) vs. Methane Pyrolysis.



Hydrogen Production from Steam Methane Reforming & Gasification

Steam Methane Reforming
Steam Methane Reforming

Traditionally, hydrogen has been generated from fossil fuels, particularly through coal gasification and Steam Methane Reforming (SMR). These methods have dominated the hydrogen production landscape, with coal gasification contributing 18% of global hydrogen production, and SMR providing a staggering 48%. However, these methods come with significant environmental drawbacks.

Coal gasification, despite its high energy efficiency of 63%, is notorious for its substantial carbon footprint, making it an unfavorable choice for sustainable hydrogen production. It produces a mixture of syngas, carbon dioxide, and hydrogen oxide, creating a challenging carbon dioxide issue.

SMR, while boasting a high energy efficiency of 75%, generates a considerable amount of carbon dioxide, emitting approximately 10 tons of CO2 for every ton of hydrogen produced. To mitigate this, carbon capture and storage (CCS) systems are introduced to separate and sequester CO2, although it reduces the net energy efficiency to 60%.

In Steam Methane Reforming (SMR) vs. Methane Pyrolysis, let's get to the know about Methane Pyrolysis in finding which is better steam methane reforming (SMR) vs. methane pyrolysis.



Methane Pyrolysis: A Sustainable Approach

Enthalpy diagrams of (A) steam methane reforming (B) methane pyrolysis. All enthalpies are taken from the National Institute of Standards and Technology (NIST), except the dissociation enthalpies.
Enthalpy diagrams of (A) steam methane reforming (B) methane pyrolysis. All enthalpies are taken from the National Institute of Standards and Technology (NIST), except the dissociation enthalpies.

Methane, the primary component of natural gas, offers an attractive source of hydrogen due to its high hydrogen-to-carbon (H/C) ratio. Thermodynamic advantage of methane pyrolysis is evident, requiring only 37.5 kJ to produce 1 mol of H2 compared to 286 kJ for water electrolysis and 63.4 kJ for SMR. While it uses natural gas as a feedstock, this technology is sustainable as it leaves no carbon impact, making it an environmentally friendly option. One crucial aspect of methane pyrolysis is its high energy efficiency, ranging from 60% to over 80% in some trials. This level of efficiency, combined with the commercial viability of the produced MWCNTs and SWCNTs, enhances the process's financial aspects, making it a more attractive choice.

Methane, the primary component of natural gas, offers an attractive source of hydrogen due to its high hydrogen-to-carbon (H/C) ratio.

In Steam Methane Reforming (SMR) vs. Methane Pyrolysis, methane pyrolysis is the low carbon output method. Let's get to know it in brief, below.



Steam Methane Reforming (SMR) vs. Methane Pyrolysis: Overview


Steam Methane Reforming (SMR) vs. Methane Pyrolysis: overview. As the world seeks cleaner and more sustainable sources of hydrogen, methane pyrolysis has emerged as a promising solution. Its significantly lower carbon impact, high energy efficiency, and the potential to produce valuable carbon products (SWCNTs &MWCNTs) make it an attractive contender in the quest for green hydrogen. By embracing this technology, we can address the scarcity of hydrogen from renewable sources while contributing to a cleaner and more sustainable energy landscape. Methane pyrolysis represents a crucial step forward in the transition to a greener future.

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